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Abstracts Book - IMRC 2018

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• SA4-P015<br />

CONFORMAL DEPOSITION OF SILICON OXIDE ON Si PLATEAUS BY<br />

TEOS-LPCVD<br />

Maria de Los Angeles de la Cruz García 1 , Enrique Quiroga González 2 , Estela Gomez Barojas 1<br />

1 Benemerita Universidad Autonoma de Puebla, Dispositivos semiconductores, Mexico.<br />

2<br />

Benemerita Universidad Autonoma de Puebla, Instituto de Física, Mexico.<br />

The step coverage of dielectrics is important for the microelectronics industry,<br />

especially for the production of 3D circuits or structures. Very often the goal is<br />

to provide highly conformable films; for example, if the goal is the fabrication of<br />

3D MOS structures, where the dielectric must conformably cover a structured Si<br />

substrate. A common process that allows this feature is the chemical vapor<br />

deposition at low pressure (LPCVD). The precursor materials commonly used for<br />

oxide fillings in LPCVD have been SiH4 and Si2H6, which are toxic and highly<br />

flammable gases. A safer alternative is the use of Tetraethylorthosilicate (TEOS<br />

- Si(OC2H5)4). Although this is an important feature of TEOS as precursor, its most<br />

important attribute is the higher probability to obtain conformal films than with<br />

the standard gas Si precursors. Nevertheless, these last features have not been<br />

exploited for the deposition of Si oxides in commercial devices. In particular,<br />

TEOS has not been tested for deposition on three-dimensional structures such<br />

as plateaus. In this work, an LPCVD system with planar deposition chamber<br />

(allowing laminar flow) and with an evaporator of TEOS, is used for the<br />

deposition of the films. The deposition was performed at 650 o C and pressure<br />

ranging 75 to 300 mbar. The homogeneity and low roughness of the films is<br />

confirmed by AFM and ellipsometry, characteristics that are important for<br />

conformal deposition.<br />

Acknowledgment:<br />

This work has been partially supported by Benémerita Universidad Autónoma<br />

de Puebla through the VIEP-Project: GOBE-EXC18-G, and through the CONACyT<br />

project CB-2014-01-243407. M. A. De la Cruz-García thanks CONACYT for a<br />

graduate student scholarship.<br />

Keywords: TEOS, conformal deposition, LPCVD system<br />

Presenting authors email: a.delacruzgarcia.3@gmail.com

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