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Thermal Behavior and Kinetic Parameters Estimation for Ulva intestinalis<br />

Torrefaction using Thermogravimetric Analyzer<br />

Raiha binti Ahmad Samawe<br />

Supervisor: Dr Nur Farizan binti Munajat<br />

Bachelor of Applied Science (Electronics and Instrumentation Physics)<br />

School of Ocean Engineering<br />

Macroalgae has been recognized as a potential biomass source but it is not fully utilized<br />

as for its high moisture content. In this study, the thermal decomposition and kinetic<br />

parameters of Ulva intestinalis torrefaction were conducted using Thermogravimetric<br />

Analyzer (TGA). The torrefaction temperature and residence time were varied from<br />

200 to 300°C and from 30 to 90 minutes, respectively with heating rate ranging from<br />

10 to 30°C/min. The functional group of the torrefied U. intestinalis was investigated<br />

using Fourier Transform Infrared (FTIR) spectroscopy. The TGA curves indicated the<br />

weight loss of the macroalgae increased as the residence time and temperature<br />

increased. The FTIR results showed the functional groups changed as temperature<br />

and time increased. The activation energies for the torrefaction were estimated by<br />

Kissinger method to be in the range of 0.3575 to 48.4058kJ/mol. This result is<br />

important to estimate the torrefaction process and the parameters for U. intestinalis<br />

biomass.<br />

178 | U M T U N D E R G R A D U A T E R E S E A R C H D A Y 2 0 1 9

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