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Determination of Hydrocarbons in Marine Core Sediments off Tioman<br />

Island<br />

Nur Shahirah Binti Rozmi<br />

Supervisor: Prof Dr. Norhayati Binti Mohd Tahir<br />

Bachelor of Science (Analytical and Environmental Chemistry)<br />

School of Marine and Environmental Sciences<br />

Universiti Malaysia Terengganu<br />

A study was carried out on selected areas off Tioman Island to determine the<br />

distribution and possible sources of hydrocarbons in core sediments. TOC was<br />

determine using Walkey-Black method. N-alkanes and polycyclic aromatic<br />

hydrocarbons (PAH) were extracted using ultrasonic extraction and analyzed using<br />

GC-MS. TOC values ranged between 0.15 - 0.99%. Distribution of n-alkanes (odd to<br />

even; C10-C33; Cmax: C16, C21, C31) suggested input of epicuticular higher plant<br />

waxes with Cmax predominance at C27 to C33 in the area whilst presence of shorter<br />

to mid-range dominance C16 to C21 indicated inputs of marine biogenic sources. The<br />

distribution of PAHs shows influences both pyrolytic and petrogenic contamination.<br />

Perylene found in all samples indicated the presence of diagenetic PAHs. Existence of<br />

UCM together with CPI and Pr/Phy ≤ 1 indicated the presence of petrogenic<br />

contamination in coastal station. Atmospheric deposition is also an important source<br />

of pyrolytic PAHs in the core sediments.<br />

1961 | UMT UNDERGRADUATE RESEARCH DAY 2018

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