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Effects of Polymer To Metal Oxide Nanoparticles Ratio on Antifouling<br />

Properties of Epoxy/PEDOT:PSS/Cerium Doped Zinc Oxide Coating<br />

Noor Sharina Aini Binti Mohd Nasir<br />

Supervisor: Dr. Wan Rafizah binti Wan Abdullah<br />

Bachelor of Technology (Environment)<br />

School of Ocean Engineering<br />

Universiti Malaysia Terengganu<br />

Biofouling is a major problem in naval industry as it causes costly bio-corrosion on<br />

equipment or structures. Prevention of biofouling is now possible through application<br />

of epoxy based coating containing ZnO as antifouling agent. This study focused on<br />

investigation of the antifouling properties of epoxy/PEDOT:PSS/Ce doped ZnO coating.<br />

The ZnO nanoparticles doped with 0.2 and 1.0 mol% Ce were prepared through the<br />

citrate gel method and solid state sintering. Epoxy coating formulations containing<br />

different PEDOT:PSS to nanoparticles ratio (1:1, 2:1, 3:1) were prepared using dropcasting<br />

method. The produced coatings were characterized using SEM, FTIR, antibacteria<br />

susceptibility test against Gram-negative (E.coli) and Gram-positive<br />

(S.aureus) bacteria models and methylene blue photodegradation assay under UV<br />

light irradiation. The findings showed that coating film containing 3:1 ratio of<br />

PEDOT:PSS to Ce doped ZnO nanoparticles exhibited the strongest antimicrobial<br />

against selected bacteria and the highest photocatalytic efficiency. This coating<br />

formulation is therefore has proven potential as antifouling coating.<br />

58 | U M T U N D E R G R A D U A T E R E S E A R C H D A Y 2019

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